1,2,3,4,5-cyclopentanepentayl, compd. with 1-[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2-[(1S)-1-(dicyclohexylphosphino)ethyl]-1,2,3,4,5-cyclopentanepentayl, iron salt (1:1:1)
1,2,3,4,5-cyclopentanepentayl, compd. with 1-[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2-[(1S)-1-(dicyclohexylphosphino)ethyl]-1,2,3,4,5-cyclopentanepentayl, iron salt (1:1:1)
CAS: 360048-63-1
Molecular Formula: C42H50FeO2P2
1,2,3,4,5-cyclopentanepentayl, compd. with 1-[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2-[(1S)-1-(dicyclohexylphosphino)ethyl]-1,2,3,4,5-cyclopentanepentayl, iron salt (1:1:1) - Names and Identifiers
| Name | 1,2,3,4,5-cyclopentanepentayl, compd. with 1-[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2-[(1S)-1-(dicyclohexylphosphino)ethyl]-1,2,3,4,5-cyclopentanepentayl, iron salt (1:1:1) |
| Synonyms | (R)-1-{(S)-2-[Bis(4-Methoxy-3,5-diMeth (R)-1-{(S)-2-[Bis(4-methoxy-3,5-dimethylphenyl)phosphino]ferrocenyl}ethyldicyclo (R)-(-)-1-[(S)-2-(Di(3,5-Dimethyl-4-Methoxyphenyl)Phosphino)Ferrocenyl]Ethyldicyclohexylphosphine (R)-(-)-1-[(S)-2-(DI(3,5-DIMETHYL-4-METHOXYPHENYL)PHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE (R)-(-)-1-{(S)-2-[Bis(3,5-diMethyl-4-Methoxyphenyl)phosphino]ferrocenyl}ethyldicyclohexylphosphine |
| CAS | 360048-63-1 |
| InChI | InChI=1/C37H51O2P2.C5H5.Fe/c1-25-21-32(22-26(2)36(25)38-6)41(33-23-27(3)37(39-7)28(4)24-33)35-20-14-19-34(35)29(5)40(30-15-10-8-11-16-30)31-17-12-9-13-18-31;1-2-4-5-3-1;/h14,19-24,29-31H,8-13,15-18H2,1-7H3;1-5H;/t29-;;/m0../s1 |
1,2,3,4,5-cyclopentanepentayl, compd. with 1-[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2-[(1S)-1-(dicyclohexylphosphino)ethyl]-1,2,3,4,5-cyclopentanepentayl, iron salt (1:1:1) - Physico-chemical Properties
| Molecular Formula | C42H50FeO2P2 |
| Molar Mass | 704.65 |
| Specific Rotation(α) | -270° ±10° (c 0.5, CHCl3) |
| Appearance | Powder |
| Color | orange |
| Storage Condition | under inert gas (nitrogen or Argon) at 2-8°C |
1,2,3,4,5-cyclopentanepentayl, compd. with 1-[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2-[(1S)-1-(dicyclohexylphosphino)ethyl]-1,2,3,4,5-cyclopentanepentayl, iron salt (1:1:1) - Risk and Safety
| WGK Germany | 3 |
| HS Code | 29319090 |
1,2,3,4,5-cyclopentanepentayl, compd. with 1-[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2-[(1S)-1-(dicyclohexylphosphino)ethyl]-1,2,3,4,5-cyclopentanepentayl, iron salt (1:1:1) - Introduction
1,2,3,4,5-cyclopentanepentayl, compd. with 1-[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2-[(1S)-1-(dicyclohexylphosphino)ethyl]-1,2,3,4,5-cyclopentanepentayl, an organometal C52H70FeP3O6 (1:1).
The compound has the following properties:
-Appearance: It is solid at room temperature, and in most cases it is light brown crystals or orange powder.
-Melting point: about 120-130°C.
-Solubility: Good solubility in common organic solvents.
This compound is mainly used for chiral ligands in metal catalyzed reactions. Its structure contains organophosphine ligands and ferrocene ligands, which are able to form stable complexes with transition metals and play a chiral-induced role in catalytic reactions.
The compound can be synthesized in two steps. First, 1,2,3,4, 5-cyclopentane pentaol and 4-methoxy-3, 5-xylylammonium bromide are reacted by reaction to obtain [(4-methoxy-3, 5-xylyl) ammonium bromide] penta-negative cyclopentane bromide compound. Then, the [(4-methoxy-3, 5-xylyl) ammonium bromide] penta-negative bromide cyclopentane compound is reacted with (S)-1,2-di (cyclohexylphosphino) ethane in acetonitrile to produce (R)-1-{(SP)-2-[bis (4-methoxy-3, 5-xylyl) phosphine] ferrocenyl} ethyldicyclohexylphosphine.
Regarding safety information, as there is no specific literature to refer to, it is not possible to provide detailed safety information and specific risks of chemicals. However, when handling chemicals, follow laboratory safety practices and take appropriate personal protective measures, such as wearing gloves, goggles, and laboratory coats. Before using the chemical, the safety data sheet provided by the supplier should be read carefully and the instructions should be followed. If you have any questions or need further information, please consult your chemical supplier.
The compound has the following properties:
-Appearance: It is solid at room temperature, and in most cases it is light brown crystals or orange powder.
-Melting point: about 120-130°C.
-Solubility: Good solubility in common organic solvents.
This compound is mainly used for chiral ligands in metal catalyzed reactions. Its structure contains organophosphine ligands and ferrocene ligands, which are able to form stable complexes with transition metals and play a chiral-induced role in catalytic reactions.
The compound can be synthesized in two steps. First, 1,2,3,4, 5-cyclopentane pentaol and 4-methoxy-3, 5-xylylammonium bromide are reacted by reaction to obtain [(4-methoxy-3, 5-xylyl) ammonium bromide] penta-negative cyclopentane bromide compound. Then, the [(4-methoxy-3, 5-xylyl) ammonium bromide] penta-negative bromide cyclopentane compound is reacted with (S)-1,2-di (cyclohexylphosphino) ethane in acetonitrile to produce (R)-1-{(SP)-2-[bis (4-methoxy-3, 5-xylyl) phosphine] ferrocenyl} ethyldicyclohexylphosphine.
Regarding safety information, as there is no specific literature to refer to, it is not possible to provide detailed safety information and specific risks of chemicals. However, when handling chemicals, follow laboratory safety practices and take appropriate personal protective measures, such as wearing gloves, goggles, and laboratory coats. Before using the chemical, the safety data sheet provided by the supplier should be read carefully and the instructions should be followed. If you have any questions or need further information, please consult your chemical supplier.
Last Update：2024-04-10 22:29:15
![1,2,3,4,5-cyclopentanepentayl, compd. with 1-[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2-[(1S)-1-(dicyclohexylphosphino)ethyl]-1,2,3,4,5-cyclopentanepentayl, iron salt (1:1:1)](http://res.chembk.com/assets/str/2d/3/36/360048-63-1.png)
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Product Name: (R)-1-{(SP)-2-[Bis(4-methoxy-3,5-dimethylphenyl)phosphino]ferrocenyl}ethyldicyclohexylphosphine Visit Supplier Webpage Request for quotation
CAS: 360048-63-1
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Mobile: 18021002903
QQ: 3008007409
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CAS: 360048-63-1
Tel: 18301782025
Email: 3008007409@qq.com
Mobile: 18021002903
QQ: 3008007409
Wechat: 18301782025
View History
1,2,3,4,5-cyclopentanepentayl, compd. with 1-[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2-[(1S)-1-(dicyclohexylphosphino)ethyl]-1,2,3,4,5-cyclopentanepentayl, iron salt (1:1:1)
2-(1,3-benzothiazol-2-yl)-2-[2-[[4-(morpholin-4-ylmethyl)phenyl]methoxy]pyrimidin-4-yl]acetonitrile
1-Piperazinesuccinimide,N-ethyl-4-methyl-(8CI)
1,3-Di(4-imidazolinophenoxyl)propane
毛冬青皂苷B2标准品
化合物DIHYDROSAMIDIN
14866-11-6
2-(1,3-benzothiazol-2-yl)-2-[2-[[4-(morpholin-4-ylmethyl)phenyl]methoxy]pyrimidin-4-yl]acetonitrile
1-Piperazinesuccinimide,N-ethyl-4-methyl-(8CI)
1,3-Di(4-imidazolinophenoxyl)propane
毛冬青皂苷B2标准品
化合物DIHYDROSAMIDIN
14866-11-6